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David Nunes Carvalho (September 29, 1848 - June 29, 1925) was an American ink and handwriting expert who provided testimony in notable legal cases and was the author of Forty Centuries of Ink, a book about ink analysis.
The British government advertises for tenders each year, the requirements for black writing ink in 1889 reads: "To be made of Best Galls, Sulphate of Iron, and Gum. The Sulphate of Iron not to exceed in quantity one-third of the weight of the Galls used, and the specific gravity of the matured Ink not to exceed 1045 degrees (distilled water being 1000 degrees)." That of Black Copying Ink "To be made of the above materials, but of a strength one fourth greater than the Writing Ink, and with the addition of Sugar or Glycerine. The specific gravity of the matured Ink not. to exceed 1085 degrees." And that of Blue-Black Writing Ink "To be made of finest Galls, Sulphate of Iron, Gum, Indigo, and Sulphuric Acid. The specific gravity of the Ink when matured not to exceed 1035 degrees.